Optimisation of surface quality retention during the thermal processing of conduction heating foods using variable temperature retort profiles.

Noronha, J.; Hendrickx, M.; Suys, J. and Tobback, P.

Optimal variable retort temperature profiles (VRT) for the sterilisation of conduction heated foods were calculated using a quasi-Newton multi-variable optimisation algorithm considering both the maximisation of surface quality and the minimisation of total process time. When the maximisation of surface quality was the objective an increase up to 20% in quality retention was predicted for optimal VRT profiles as compared to optimal constant retort temperature profiles (CRT). When considering the minimisation of total process time the use of VRT profiles allowed to reduce the total process time up to 45% still providing the same surface quality as optimal CRT. Since the results could not be generalised, it was concluded that optimal VRT profiles should be calculated on a case by case basis.

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Simultaneous Optimisation of Surface Quality for Three Components during the Sterilisation of Conductive Heating Foods using Constant and Variable Retort Temperature Profiles.

Noronha, J.; Van Loey, A.; Hendrickx, M. and Tobback, P.

The feasibility of the simultaneous optimisation of surface quality of three quality factors presenting different activation energies was investigated for the sterilisation of conduction heating foods using a computer simulation approach.

Optimal constant and variable retort temperature profiles were calculated considering the maximisation of surface retention for each of the individual quality factors and considering the simultaneous maximisation of the retention of the three components. Optimal variable retort profiles that allow the minimisation of the process time still providing overall final surface retention similar to the optimum constant retort temperature where also calculated.

It was found that the use of optimum variable retort profiles allows the simultaneous optimisation of three quality factors, where the final surface retention of each quality attribute is higher than those calculated based on optimum constant temperature profiles. Moreover it was found that the use of variable retort temperature profiles allows substantial reductions in process time still providing final surface retention of the individual quality factors comparable to those obtained using the more time consuming constant temperature profiles.

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Determination of Appropriate Heat Penetration Parameters for the Evaluation of Process Deviations During In-Pack Sterilisation of Foods

Noronha, J., Van Loey, A., Stoforos, N.G. Hendrickx, M. and Tobback, P.

Methods for the determination of appropriate heat penetration parameters to be used with semi-empirical methods for the determination of product temperature evolution during the sterilisation of packed foods in batch type retorts are presented. The heat penetration parameters determined are used with semi-empirical methods for the determination of the temperature evolution for the evaluation of process deviations consisting on temperature drops on the scheduled processing temperature.

The proposed methods for the determination of appropriate heat penetration parameters were able to calculate heat penetration parameters independent of the duration and shape of the retort come-up-time. The use of the determined heat parameters allowed an accurate evaluation of process deviations in a retort simulator during the thermal processing of food simulants. A good agreement between experimental and predicted product temperatures could be achieved. A good agreament between processing values calculated from experimental measured temperature profiles and from predicted temperature profiles could be found.

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Experimental Validation of Mathematical Procedures for the Evaluation of Thermal Processes and Process Deviations During the Sterilisation of Canned Foods

Tucker, Gary S.; Noronha, João F. and Heydon, Camilla J.

In this article mathematical models for the design and evaluation of in-pack sterilisation processes including the evaluation of process deviations consisting of drops in the ambient temperature are discussed. Models for simulating conduction heating, broken heating and convection heating are considered. The methodologies used in the determination of the empirical parameters associated with the proposed methods are briefly discussed.

The methods are validated against experimental data obtained by processing real foods in a retort simulator. Results for beans in tomato sauce, chicken cream soup and peas in brine, processed in A1 metal cans (65 mm diameter x 102 mm height), meat chunks in gravy processed in UT cans (73 mm diameter x 115 mm height) and fish processed in Dingley cans (105 mm x 17 mm x 15 mm) were used in the validation trials. fh values ranged from 4.5 min to 38.8 minutes. Both "normal" and "deviant" processes were considered. A good agreement between experimental and simulated data was achieved in terms of predicted temperatures. Calculated processing values agreed with experimental values within 30% for the cases presented.

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Alternative algorithms for evaluation of process deviations in batch-type sterilisation processes.

Noronha, J .; Van Loey, A.; Hendrickx, M. and Tobback, P.

Process deviations during the thermal processing of non-conductive heating foods are difficult to handle. The commonly used formula methods (Ball, Hayakawa) are restricted to processing conditions existing of a come-up time, a holding period at constant heating medium temperature followed by cooling, leading to log-linear heating of the container. Numerical equations for the Fourier heat equations are available but not directly useful to non-conduction problems. An approach using an apparent thermal diffusivity to simulate the heating rate of the product (fh) and a time correction factor to allow changes in the lag-factor (j-value) has recently been proposed by Teixeira et al. (1992).

This paper discusses alternative empirical, analytical and numerical approaches to handle process deviations. Empirical equations (Hayakawa) and analytical solutions are used together with the Duhamel theorem to handle variable boundary conditions. In the context of these methods, a new procedure for determination of heating parameters fh and j is described. The performance of these methods for determination of heating characteristics and evaluation of process deviations is tested against theoretically generated case studies and experimental data obtained on food (model) systems in a pilot retort.

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New semi-empirical approach to handle time-variable boundary conditions during sterilisation of non-conductive heating foods.

Noronha, J.; Hendrickx, M.; Van Loey, A. and Tobback, P.

Semi-empirical methods for the prediction of time temperature histories in conductive and non conductive (convective and mixed mode) heating foods subjected to a time variable processing temperature are proposed. Four alternatives are considered: (i) Hayakawa's method (Duhamel's theorem with Hayakawa's formulas) (ii) Duhamel's theorem with analytical solution (iii) Numerical solution with apparent time (time shift) (iv) Numerical solution with apparent position. The incorporation of the empirical heating characteristics f and j in conductive models was accomplished by evaluating the existing analogies with thermophysical properties in the solutions of the Fourier equation. Approaches using Duhamel's theorem or finite difference solutions were used to handle variable boundary conditions. The application of the models in the calculation of processing values for thermal processes with different come up times and different boundary conditions during come up time and thermal processes with process deviations is discussed. The numerical solution with apparent position was preferred because it combines accuracy and flexibility.

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Simultaneous optimisation of surface quality during the sterilisation of packed foods using constant and variable retort temperature profiles

Noronha, J.; Hendrickx, M. and Tobback, P.

The differences in temperature dependence between spore inactivation and degradation of quality factors allow the optimisation of thermal processes in terms of maximisation of quality retention by choosing an optimum heating profile. While the maximisation of the retention for a single quality factor has received considerable attention in research, the possibilities of simultaneously maximising the retention of different quality factors has up to now not been addressed.

In this article the possibilities of the simultaneous optimisation for more than one quality factors were theoretically assessed. Both the use of constant and variable retort temperature profiles were considered. A special emphasis was given to the formulation of appropriate objective functions for the simultaneous optimisation of the surface retention of quality factors.

For the simultaneous optimisation of quality factors the objective functions should be formulated in terms of maximising final retention and not, as in the case of single component optimisation, in terms of minimisation of cook values. The use of variable retort temperature profiles was shown to be particularly interesting for the simultaneous optimisation of more than one quality factor, as the final retention calculated compared well with the maximum retention achieved using individual calculated optimum constant retort temperature control for each of the components.

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An empirical equation for the description of the optimum profiles that maximise surface quality retention of thermally processed foods

Noronha, João Freire de; Hendrickx, Marc and Tobback, Paul

It has been previously shown that, when compared with the traditional constant retort temperature profiles, variable retort temperature profiles allow a substantial increase in quality retention during the sterilisation of packed foods. When the minimisation of the process time with a constraint on the minimum surface quality is considered, variable retort policies show significant reductions on process times when compared to equivalent optimum constant retort temperature profiles. However the results were presented on a case by case basis and no effort was done to try to generalise this principle.

In order to allow the generalisation of the use of variable profiles we present in this article an empirical formula, developed based on the analysis of calculated optimum variable retort temperature profiles, that allows an accurate description of optimum variable temperature profiles. The use of the proposed equation allows a substantial reduction on the calculation effort necessary for the calculation of optimum variable retort temperature profiles.

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Optimizing thermal process for canned white beans in water cascading retorts.

Van Loey, A.; Fransis, A.; Hendrickx, M.; Maesmans, G.; Noronha, J. and Tobback, P.

Based on thermal degradation kinetics and heat transfer expressed as the Ball formula method, a simplified approach was used to optimize sterilization processes for thermal softening of white beans (Phaseolus vulgaris, subsp. nanus Metz., variety Manteca de Leon). Constant retort profiles in a still and end-over-end rotary water cascading retort (Barriquand Steriflow) were used. Quality attributes of beans processed at the optimum were evaluated by a trained taste panel and by a tenderometer. Both approaches could distinguish (P < 0.01) between attributes of products from optimal rotary and still processes. End-over-end rotation resulted in faster heat penetration and better quality retention of beans. Texture of white beans processed at 4 degrees or 8 degrees C from the optimal temperature could be distinguished (P < 0.01) by the sensory panel and by the tenderometer.

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Evaluation of the integrated time-temperature effect in thermal processing of foods.

Hendrickx, M., Maesmans, G., De Cordt, S., Noronha, J., Van Loey, A. and Tobback, P.

 In this review, current methods used to evaluate the integrated impact of time and temperature upon preserving a food product by a heat treatment are considered. After identifying the basic premise any preservation scheme shall meet, the central role of a feasible description for the heat activation kinetics of microorganisms, their spores, and other quality attributes are stressed. Common concepts to quantify a thermal process are presented. Shortcomings of the prevalent evaluation methods are highlighted and attention is given to the development, restrictions, and possibilities of time-temperature-integrators as "new" evaluation tools to measure the impact of a "classical" in-pack heat treatment and more modern heating techniques such as continuous processing of solid, liquid mixtures on foods.

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Evaluation of Process deviations, consisting of drops in rotational speed during thermal processing of foods in rotary water cascading retorts

Denys, S.; Noronha, J.; Stoforos, N.G.; Hendrickx, M. and Tobback, P.,

 Taking into account the similarities of broken-line heating curves and heat-penetration curves obtained when a product undergoes a drop in rotational speed during thermal processing in a rotary water cascading retort, a semiempirical method used for handling broken-line heating behaviour is suggested as a method of dealing with this type of process deviation. For this purpose, the possibility of extrapolating the empirical heating rate parameter fh, determined on the heat-penetration curve of white beans in brine processed in a still retort, to the 'still' conditions associated with a rotational speed drop in a rotary water cascading retort, was investigated. Following this approach, safe product temperature predictions were obtained. The main criterion influencing the quality of the evaluation was the determination of the correct empirical parametric value to be used. This means, when determining this parametric value, care is required when selecting the correct temperature interval on the heat-penetration curve.

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Inverse superposition for calculating food product temperatures during in-container thermal processing.

Stoforos, N.G, Noronha, J., Hendrickx, M. and Tobback, P.

 A procedure was developed for theoretical calculation of internal product temperatures during in-container sterilization of foods. Experimental product temperatures were determined through traditional heat penetration tests (processing in a retort with come-up time of increasing temperature and holding time at constant temperature). These were used to produce, through a proposed inverse superposition solution, a "standardized," normalized, dimensionless product temperature curve corresponding to the response of product temperature to a constant retort temperature profile. This "standardized" curve was then used, through Duhamel's superposition theorem, to calculate product temperatures for time-varying retort temperature profiles. Limitations associated with the application of Duhamel's theorem were also transferred to the proposed methodology. Theoretical, for perfect mixing, and experimental, for conduction heating, data were used in example calculations.

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A semi-empirical approach to handle broken-line heating: Determination of empirical parameters and evaluation of process deviations.

Denys, S.; Noronha, J.; Stoforos, N.G.; Hendrickx, M. and Tobback, P.

 An existing semi-empirical model for simulating product temperature profiles during thermal processing of conduction or convection heating foods under time varying boundary conditions (variable retort temperatures) was extended for the case of broken-line heating products. The use of the method for determination of the empirical heat penetration parameters for broken-line heating curves as defined by Ball (jh, fhl, fh2, xbh) was evaluated. Starch solutions, showing broken-line heating behavior, were used as a food simulant. To investigate the consistency of the determined broken-line heating parameters, and to test the applicability of the method when boundary conditions are time dependent, process deviations consisting of drops on the heating medium temperature during the holding phase of a process were evaluated. The model is a promising approach, if the correct empirical parameters are used.

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A critical analysis of mathematical procedures for the evaluation and design of in-container thermal processes for foods.

Stoforos, N.G., Noronha, J., Hendrickx, M. and Tobback, P.

Kinetic data on thermal destruction of spoilage and quality factors coupled with the temperature history of a product during a heat sterilization cycle are the basic information needed for the evaluation and the design of thermal processes through a physical-mathematical approach. A critical review on the available physical- mathematical procedures used for thermal process calculations of in-container processed foods is presented. The origin and the limitations of each method are discussed. The equations associated with each method, for internal product temperature predictions, are explicitly given. The relative performance of selected methods under identical processing conditions is illustrated. Several problems associated with thermal process calculations are discussed.

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AGRO44- Development of a common understanding of HACCP in traditional cheese-dairies

João Freire de Noronha

Food Science and Techonology Department, Escola Superior Agraria de Coimbra. Bencanta - 3040-116 Coimbra, Portugal; noronha@mail.esac.pt

In this poster we will introduce an ongoing project (AGRO 44, started in March 2002) aimed at the dissemination of GMP/GHP/SOP and HACCP in the manufacturing of DOP cheeses produced in the central region of Portugal. The main goal of this project is the development of a common understanding of HACCP among the producers, the technicians from the Portuguese food regulatory authorities (responsible for approving, licensing and controlling HACCP correct implementation) and academia.

The project is being developed in five main areas: (i) Development of a GMP/GHP Manual for milk production (farm); (ii) Development of a GMP/GHP/SOP Manual for small (micro) traditional cheese-dairies; (iii) Implementation of HACCP in selected cheese-dairies (demonstration plants) (iv) Development of Generic HACCP Plans for the production of cheese; and (v) Development of an Internet site for the dissemination of all the produced material.

The participant institutions (academia, regulatory/inspection authorities, producer associations and a local rural development agency) will promote various actions in order to make the collected information available to the final users (milk and cheese producers).

AGRO44 is funded by the AGRO Program (Measure 8, Action 8.1) from the Portuguese Ministry of Agriculture.

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Elaboração de uma lista de descritores para queijos tradicionais portugueses

Carmen Santos e João Noronha

Departamento de Ciência e Tecnologia Alimentares. Escola Superior Agrária de Coimbra. Bencanta. 3040-116 Coimbra. noronha@mail.esac.pt  Tel. 239 802 276

Neste trabalho descreve-se a elaboração de uma lista de descritores para a análise sensorial descritiva de queijos tradicionais portugueses. Este trabalho foi realizado no âmbito do projecto “AGRO 243 - Caracterização sensorial de queijo e requeijão elaborados a partir do leite de ovinos e caprinos da região centro. Aplicação ao queijo da Serra Velho e Requeijão”.

Para a elaboração da lista de descritores foi seleccionado um painel inicial de 50 elementos com experiência diversificada na participação em provas sensoriais. Após um período inicial de treino e adaptação à metodologia de análise sensorial utilizando uma metodologia adaptada da NP ISO 8586-1 (Análise sensorial – Guia geral para a selecção, treino e controlo dos provadores. Parte 1: Provadores Qualificados), procedeu-se à elaboração da lista de descritores seguindo a metodologia proposta na norma ISO 11035:1994 (Sensory analysis – Identification and selection of descriptors for establishing a sensory profile by a multidimensional approach).

Este trabalho foi apoiado pelo Programa AGRO, Medida 8 - Desenvolvimento Tecnológico e Demonstração,Acção 8.1 - Desenvolvimento Experimental e Demonstração (DE&D).

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